HIGHLY SOLVATOCHROMIC EMISSION OF ELECTRON-DONOR ACCEPTOR COMPOUNDS CONTAINING PROPANEDIOATO BORON ELECTRON-ACCEPTORS

被引：10

作者：

BROUWER, AM

BAKKER, NAC

WIERING, PG

VERHOEVEN, JW

机构：

[1] Laboratory of Organic Chemistry, University of Amsterdam, 1018 WS Amsterdam

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 16期

关键词：

D O I：

10.1039/C39910001094

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Light-induced electron transfer occurs in bifunctional compounds consisting of 1,3-diphenylpropanedioato boron oxalate or fluoride electron acceptors and simple aromatic electron-donor groups, linked by a methylene bridge; fluoresence from the highly polar charge-transfer excited state is remarkably efficient and shows an exceptionally large solvatochromicity.

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页码：1094 / 1096

页数：3

相关论文

共 20 条

[1] MULTISTEP PHOTOINDUCED ELECTRON-TRANSFER IN A PHOTOACCEPTOR TERMINATED MOLECULAR TRIODE [J].

BAKKER, NAC ;

WIERING, PG ;

BROUWER, AM ;

WARMAN, JM ;

VERHOEVEN, JW .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 183 :31-40

[2] DIPOLAR NATURE OF MOLECULAR COMPLEXES FORMED IN EXCITED STATE [J].

BEENS, H ;

KNIBBE, H ;

WELLER, A .

JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (03) :1183-&

[3] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[4]

FOX MA, 1984, J ORG CHEM, V49, P1971

[5] A SIMPLE ROUTE TO A NEW TYPE OF BORON-CONTAINING SPIROCOMPOUNDS [J].

HARTMANN, H .

JOURNAL FUR PRAKTISCHE CHEMIE, 1986, 328 (5-6) :755-762

[6] SYSTEMATIC STUDY OF A SERIES OF HIGHLY FLUORESCENT ROD-SHAPED DONOR-ACCEPTOR SYSTEMS [J].

HERMANT, RM ;

BAKKER, NAC ;

SCHERER, T ;

KRIJNEN, B ;

VERHOEVEN, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (03) :1214-1221

[7]

HERMANT RM, 1990, THESIS U AMSTERDAM

[8] ELECTRON-TRANSFER FROM AROMATIC-HYDROCARBONS AND THEIR PI-COMPLEXES WITH METALS - COMPARISON OF THE STANDARD OXIDATION POTENTIALS AND VERTICAL IONIZATION-POTENTIALS [J].

HOWELL, JO ;

GONCALVES, JM ;

AMATORE, C ;

KLASINC, L ;

WIGHTMAN, RM ;

KOCHI, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (14) :3968-3976

[9] SPECTROSCOPY, PHOTOPHYSICS AND PHOTOCHEMISTRY OF 1,3-DIKETOBORONATES .6. THE EXCIPLEXES OF 2-NAPHTHYL-SUBSTITUTED 1,3-DIKETOBORONATES [J].

ILGE, HD ;

KOZMENKO, MV ;

KUZMIN, MG .

JOURNAL OF PHOTOCHEMISTRY, 1987, 36 (01) :27-37

[10]

JENNESKENS LW, 1989, RECL TRAV CHIM PAY B, V108, P453