A STUDY OF THE INTERPHASE STRUCTURE AT THE OXIDE METAL INTERFACE IN THE CORROSION OF ZIRCONIUM-BASED ALLOYS

被引:21
作者
DING, YQ
NORTHWOOD, DO
机构
[1] Engineering Materials Group, Mechanical Engineering Department, University of Windsor, Windsor
关键词
D O I
10.1016/0010-938X(94)90157-0
中图分类号
T [工业技术];
学科分类号
08 [工学];
摘要
The nature of the oxide layer that formed during corrosion of zirconium-based alloys in a pressurized, lithiated water environment at 300 degrees C was determined through scanning electron microscopy (SEM) study of the oxide-metal interface region as well as X-ray diffraction (XRD) and electron diffraction (ED) analyses. Alloys examined included cold-worked Zr-2.5wt%Nb, heat-treated Zr-2.5wt%Nb, Excel alloy (Zr-Sn-Mo-Nb), pure zirconium and cold-worked Zircaloy-4 (Zr-Sn alloy). The metallographic observations and corrosion kinetics studies show that variations in the oxidation rate among the zirconium-based alloys result from the differences in structure of the interphase layer at the oxide-metal interface
引用
收藏
页码:259 / 282
页数:24
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