BILE PIGMENT STUDIES .5. SOME FRAGMENTATION REACTIONS OF BILINDIONES (BILITRIENES)

被引：12

作者：

EIVAZI, F ^{[1
]}

SMITH, KM ^{[1
]}

机构：

[1] UNIV LIVERPOOL, ROBERT ROBINSON LABS, LIVERPOOL L69 3BX, LANCASHIRE, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 02期

关键词：

D O I：

10.1039/p19790000544

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anodic oxidation of the model bilindione (1) at platinum electrodes in the presence of methanol gives a good yield of the 15,16-dimethoxybilindione (3). With nickel(II) acetate, this compound gives a chelate which fragments upon treatment with acid to afford the tripyrrinone aldehyde (2) via the vinyl ether. When metal-free 3 is treated with aqueous acid 2 and 1 are obtained.

引用

页码：544 / 547

页数：4

共 16 条

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[9] BILE PIGMENT STUDIES .4. SOME NOVEL REACTIONS OF METALLOPORPHYRINS WITH THALLIUM(III) AND CERIUM(IV) SALTS - RING CLEAVAGE OF MESO-TETRAPHENYLPORPHYRIN
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