ENANTIOSELECTIVE OXIDATION BY A CHIRAL ACYLAMINYL OXIDE

被引：27

作者：

BERTI, C

PERKINS, MJ

机构：

[1] Dept. of Chemistry, Chelsea College, London, SW3 6LX, Manresa Road

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1002/anie.197908641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new oxidizing agent having remarkable properties has been found in the readily accessible chiral radical 1. It preferentially oxidizes one enantiomer of the test substances D, L‐benzil and D, L‐benzion, so thet the other enentiomer accumulates. The reactivity and enantioselectivity of 1 should be enhanced by other substituents. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：864 / 865

页数：2

共 7 条

[1] ACYL NITROXIDES .1. SYNTHESIS AND ISOLATION
ALEWOOD, PF
HUSSAIN, SA
JENKINS, TC
PERKINS, MJ
SHARMA, AH
SIEW, NPY
WARD, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1978, (09): : 1066 - 1076
[2] PARTIAL OPTICAL RESOLUTION OF A HYDROCARBON BY FREE-RADICAL KINETIC RESOLUTION
HARGIS, JH
HSU, HH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (24) : 8114 - 8115
[3] JENKINS TC, J CHEM SOC P1
[4] JENKINS TC, 1977, TETRAHEDRON LETT, P3199
[5] RESOLUTION OF BENZOIN
KENYON, J
PATEL, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JAN): : 435 - &
[6] SHARMA AK, UNPUBLISHED
[7] OXIDATIONS WITH POTASSIUM NITROSODISULFONATE (FREMYS RADICAL - TEUBER REACTION
ZIMMER, H
LANKIN, DC
HORGAN, SW
[J]. CHEMICAL REVIEWS, 1971, 71 (02) : 229 - &

← 1 →