IN-SITU FT-IR SPECTROELECTROCHEMICAL STUDY OF THE TRINUCLEAR COMPLEX [RU-3(MU(3)-O)(MU-CH3COO)(6)(CO)(PYRIDINE)(2)] IN ACETONITRILE

被引：43

作者：

YE, S ^{[1
]}

AKUTAGAWA, H ^{[1
]}

UOSAKI, K ^{[1
]}

SASAKI, Y ^{[1
]}

机构：

[1] HOKKAIDO UNIV, GRAD SCH SCI, DIV CHEM, SAPPORO, HOKKAIDO 060, JAPAN

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 18期

关键词：

D O I：

10.1021/ic00122a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The in-situ FT-IRRAS (Fourier transform infrared reflection absorption spectroscopy) technique has been applied to measure the nu(CO) values of the four oxidation states of the multistep redox system [Ru-3(mu(3)-O)(mu-CH3COO)(6)(CO)(pyridine)(2)](n+), in acetonitrile, of which only the n = 0 state has been isolated as a stable solid. The nu(CO) values for the n = -1, 0, +1, and +2 states are 1900, 1940, 2055, and 2110 cm(-1), respectively, indicating the approximate oxidation states of the Ru ion with CO are II, II, III, and III, respectively.

引用

页码：4527 / 4528

页数：2

共 29 条

[1] REVERSIBLE MULTISTEP AND MULTIELECTRON REDOX BEHAVIOR OF AN OXO-CENTERED TRINUCLEAR RUTHENIUM COMPLEX WITH A REDOX-ACTIVE LIGAND, [RU-3(MU(3)-O)(MU-CH3CO2)(6)(MBPY(+))(3)](4+)(MBPY(+)=N-METHYL-4,4'-BIPYRIDINIUM ION), AND ITS TRIRHODIUM AND DIRUTHENIUM-RHODIUM DERIVATIVES [J].

ABE, M ;

SASAKI, Y ;

YAMADA, Y ;

TSUKAHARA, K ;

YANO, S ;

ITO, T .

INORGANIC CHEMISTRY, 1995, 34 (17) :4490-4498

[2] KINETIC-STUDIES ON THE TERMINAL PYRIDINE EXCHANGE-REACTIONS OF SOME OXO-ACETATE BRIDGED TRINUCLEAR RUTHENIUM COMPLEXES - INFLUENCE OF THE METAL OXIDATION-STATE AND NON-LEAVING TERMINAL LIGAND (CO) [J].

ABE, M ;

SASAKI, Y ;

NAGASAWA, A ;

ITO, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (05) :1411-1414

[3] X-RAY STRUCTURE, LIGAND SUBSTITUTION, AND OTHER PROPERTIES OF TRINUCLEAR RUTHENIUM COMPLEX, [RU3(MU-3-O)(MU-C6H5COO)6(PY)3](PF6) (PY=PYRIDINE), AND X-RAY STRUCTURE OF DINUCLEAR RUTHENIUM COMPLEX, [RU2(MU-C6H5COO)4CL] [J].

ABE, M ;

SASAKI, Y ;

YAMAGUCHI, T ;

ITO, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (06) :1585-1590

[4]

ABE M, IN PRESS

[5] PREPARATION AND ELECTROCHEMICAL RESPONSE OF POLY(4-VINYLPYRIDINE)-COORDINATED OXO-ACETATO TRIRUTHENIUM CLUSTER FILM [J].

AKASHI, D ;

KIDO, H ;

SASAKI, Y ;

ITO, T .

CHEMISTRY LETTERS, 1992, (01) :143-146

[6] ELECTRONIC-STRUCTURE AND REDOX PROPERTIES OF CLUSTERS [RU3O(CH3CO2)6L3]N+ [J].

BAUMANN, JA ;

SALMON, DJ ;

WILSON, ST ;

MEYER, TJ ;

HATFIELD, WE .

INORGANIC CHEMISTRY, 1978, 17 (12) :3342-3350

[7] SYNTHESIS, X-RAY STRUCTURES AND INFRARED SPECTROELECTROCHEMISTRY OF ORTHOMETALLATED DERIVATIVES OF PYRROLYL COMPLEXES OF IRON AND MANGANESE FORMED BY REACTION WITH [OS3(CO)10(MECN)2] [J].

BEST, SP ;

CLARK, RJH ;

DEEMING, AJ ;

MCQUEEN, RCS ;

POWELL, NI ;

ACUNA, C ;

ARCE, AJ ;

DESANCTIS, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (04) :1111-1115

[8] THE SELECTIVE OXIDATION OF PRIMARY ALCOHOLS TO ALDEHYDES BY O-2 EMPLOYING A TRINUCLEAR RUTHENIUM CARBOXYLATE CATALYST [J].

BILGRIEN, C ;

DAVIS, S ;

DRAGO, RS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3786-3787

[9] CHEMICAL AND PHYSICAL-PROPERTIES OF TRIANGULAR BRIDGED METAL-COMPLEXES [J].

CANNON, RD ;

WHITE, RP .

PROGRESS IN INORGANIC CHEMISTRY, 1988, 36 :195-298

[10] TRIRUTHENIUM CLUSTER POLYPYRROLE FILMS - A REMARKABLY STABLE IMMOBILIZED RELAY AT HIGHLY POSITIVE POTENTIALS - ITS APPLICATION TO THE ELECTROCATALYTIC OXIDATION OF BENZYL ALCOHOL [J].

COSNIER, S ;

DERONZIER, A ;

LLOBET, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 280 (01) :213-219

← 1 2 3 →