The first ionization potential of nitrogen dioxide

被引:22
作者
Natalis, P. [1 ]
Collin, J. E. [1 ]
机构
[1] Univ Liege, Inst Chim, Lab Etude Etats Ionises, Liege, Belgium
关键词
D O I
10.1016/0009-2614(68)80053-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A detailed investigation of the ionization of NO2 by photoelectron spectroscopy at three different wavelengths leads to a first ionization potential of 8.8 eV. Vibrational structure is observed and it is shown that the measured 2016 cm(-1) ionic frequency. corresponding to nu(3) or (nu(1) + nu(2)), is indicative of the ionization of an antibonding electron.
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页码:79 / 82
页数:4
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