ENE REACTION

被引：756

作者：

HOFFMANN, HM

机构：

[1] Ralph Forster Laboratories, University College, London, W C. 1, Gower Street

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1969年 / 8卷 / 08期

关键词：

Addition; Alkenes; C−C coupling; Ene reaction;

D O I：

10.1002/anie.196905561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ene reaction is defined as the indirect substituting addition of a compound with a double bond (enophile) to an olefin with an allylic hydrogen (ene). For a long time the reaction has been neglected and has remained overshadowed by the related Diels‐Alder addition. It is shown that the ene reaction possesses wide scope and applicability ranging from industrial to biosynthetic processes. Preparative aspects are summarized and current views on the mechanism are discussed. Copyright © 1969 by Verlag Chemie, GmbH, Germany

引用

页码：556 / &

共 242 条

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