EXCESS DIFFERENTIAL THERMODYNAMIC PROPERTIES

被引：6

作者：

DAVIS, MI ^{[1
]}

DOUHERET, G ^{[1
]}

机构：

[1] UNIV CLERMONT FERRAND,THERMODYNAM & CINET CHIM LAB,CNRS,URA 434,F-63177 CLERMONT FERRAND,FRANCE

来源：

THERMOCHIMICA ACTA | 1991年 / 190卷 / 02期

关键词：

D O I：

10.1016/0040-6031(91)85253-E

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A strategy is described for the systematic generation of a complete set of partial derivatives of the four energy functions from a basis set of five measured properties: V(m), S(m), C(p,m), (delta-V(m)/delta-T)p and either (delta-V(m)/delta-p)T or (delta-V(M)/delta-p)s. The same set of equations applies to both pure substances and either real or ideal mixtures. Examples are given of some excess differential properties of binary mixtures which exhibit unusual sensitivity to changes in composition.

引用

页码：267 / 277

页数：11

共 9 条

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