INFLUENCE OF HYDROGEN-BOND CONNECTIVITY ON THE DYNAMICAL PROPERTIES OF HYDROGEN-BONDED LIQUIDS

被引：9

作者：

MIGLIARDO, P ^{[1
]}

机构：

[1] INFM,I-98166 MESSINA,ITALY

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 296卷 / 03期

关键词：

D O I：

10.1016/0022-2860(93)80138-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spectroscopic studies of H-bonded liquids in bulk and in confined geometries are presented, The examples shown (water within reversed micelles, alcohols dispersed in an inert solvent and in the normal liquid phase) provide evidence that the dynamic properties (both diffusional and vibrational) are strongly affected by the presence of the H-bond, which induces cooperative changes in the time evolution of the correlation functions.

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页码：229 / 242

页数：14

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