E-(3-TRIFLUOROMETHYL-1,3-BUTADIENYL)DI-ISOPROPOXYBORANE AS A POTENTIALLY USEFUL CF3-CONTAINING BUILDING-BLOCK - SYNTHESIS AND PALLADIUM-PROMOTED COUPLING WITH ARYL HALIDES

被引：6

作者：

JIN, FQ ^{[1
]}

XU, YY ^{[1
]}

JIANG, B ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 65卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0022-1139(00)80481-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound was synthesized from a trifluoroisopropenyl-zinc reagent and E-(2-bromoethenyl)di-isopropoxyborane. As a potentially useful building block for trifluoromethylated compounds, this trifluoromethyl-containing boron reagent underwent a palladium-catalyzed stereospecific coupling reaction with aryl halides to afford E-1-aryl-3-trifluoromethyl-1,3-butadienes.

引用

页码：111 / 114

页数：4

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