ELECTRONIC-STRUCTURE OF LINIO2, LIFEO2 AND LICRO2 - X-RAY PHOTOELECTRON AND X-RAY-EMISSION STUDY

被引：46

作者：

GALAKHOV, VR

KURMAEV, EZ

UHLENBROCK, S

NEUMANN, M

KELLERMAN, DG

GORSHKOV, VS

机构：

[1] UNIV OSNABRUCK,FACHBEREICH PHYS,D-49069 OSNABRUCK,GERMANY

[2] RUSSIAN ACAD SCI,INST CHEM SOLIDS,URAL DIV,SVERDLOVSK 620219,RUSSIA

来源：

SOLID STATE COMMUNICATIONS | 1995年 / 95卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

D O I：

10.1016/0038-1098(95)00279-0

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We present X-ray photoelectron (XPS) and soft X-ray emission (XES) spectra of LiNiO2, LiFeO2 and LiCrO2. The concentration of holes per oxygen ion in LiNiO2 is estimated and a classification of the investigated oxides is given. We propose, that LiFeO2 should be placed in the intermediate region between a charge-transfer and a Mott-Hubbard insulator and LiCrO2 can most likely be assigned to the Mott-Hubbard insulators.

引用

页码：347 / 351

页数：5

共 19 条

[1] BAND THEORY AND MOTT INSULATORS - HUBBARD-U INSTEAD OF STONER-I [J].