HIGH-RESOLUTION INFRARED-SPECTRUM OF THE NU-3 AND NU-6 BANDS OF HCF3 AND OF THEIR HOT BANDS

被引：37

作者：

GRANER, G ^{[1
]}

ANTTILA, R ^{[1
]}

KAUPPINEN, J ^{[1
]}

机构：

[1] UNIV OULU,DEPT PHYS,SF-90100 OULU 10,FINLAND

来源：

MOLECULAR PHYSICS | 1979年 / 38卷 / 01期

关键词：

D O I：

10.1080/00268977900101551

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared spectrum of fluoroform has been recorded between 480 and 730 cm-1at a resolution of 003 cm-1. The v6 perpendicular band at 507-8228 (6) cm-1, heavily perturbed by an 1(2,2) type rotational resonance, has been analysed in the P and R as well as in the Q branches. The v3 parallel band at 700-1009 (6) cm-1 has also yielded molecular constants including C-C’. Each of these bands is accompanied by hot bands among which v3+v6-v6 and 2v6-v6 deserved special attention since both the upper and lower states of these transitions are perturbed. © 1979 Taylor & Francis Group, LLC.

引用

页码：103 / 128

页数：26

共 26 条

[1] MOLECULAR VIBRATIONAL CONSTANTS OF SOME SIMPLE POLYATOMIC-MOLECULES - TRIHALOGENOMETHANES, CHX3 AND TRIHALOGENOSILANES, SIHX3 (X = F, CL, BR) [J].