OXIDATION OF ACETONE UNDER BAEYER-VILLIGER CONDITIONS - EVIDENCE FOR FORMATION OF ACETONE CARBONYL OXIDE OR ITS ISOMERIC DIOXIRANE

被引：31

作者：

MURRAY, RW

RAMACHANDRAN, V

机构：

[1] Department of Chemistry, University of Missouri — St. Louis, St Louis, Missouri

来源：

PHOTOCHEMISTRY AND PHOTOBIOLOGY | 1979年 / 30卷 / 01期

关键词：

D O I：

10.1111/j.1751-1097.1979.tb07134.x

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Abstract— Oxidation of acetone under Baeyer‐Villager conditions produces a new species which is capable of epoxidizing olefins. It is suggested that this intermediate is acetone carbonyl oxide or its isomer dimethyldioxirane. Copyright © 1979, Wiley Blackwell. All rights reserved

引用

页码：187 / 189

页数：3

共 11 条

[1] EDWARDS JO, PHOTOCHEM PHOTOBIOL
[2] MECHANISMS OF GAS-PHASE AND LIQUID-PHASE OZONOLYSIS
HARDING, LB
GODDARD, WA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (23) : 7180 - 7188
[3] Hassall C.H., 1957, ORG REACT, V9, P73
[4] OXIDATION OF DIAZO-COMPOUNDS WITH SINGLET OXYGEN - FORMATION OF OZONIDES
HIGLEY, DP
MURRAY, RW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (10) : 3330 - 3332
[5] EPOXIDATION OF OLEFINS WITH CARBONYL OXIDES
HINRICHS, TA
RAMACHANDRAN, V
MURRAY, RW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (05) : 1282 - 1284
[6] IDENTIFICATION OF DIOXIRANE (H2COO) IN OZONE-OLEFIN REACTIONS VIA MICROWAVE SPECTROSCOPY
LOVAS, FJ
SUENRAM, RD
[J]. CHEMICAL PHYSICS LETTERS, 1977, 51 (03) : 453 - 456
[7] OZONIDES FROM PHOTOOXIDATION OF DIPHENYLDIAZOMETHANE IN PRESENCE OF ALDEHYDES
MURRAY, RW
SUZUI, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (19) : 4963 - &
[8] MECHANISM OF OZONOLYSIS - NEW ROUTE TO OZONIDES
MURRAY, RW
SUZUI, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (10) : 3343 - 3348
[9] MURRAY RW, 1972, OZONE REACTIONS ORGA, P9
[10] SMITH PAS, 1963, MOL REARRANGEMENTS, P568

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