MOLECULAR THEORY OF RUBBER ELASTICITY

被引：456

作者：

FLORY, PJ

机构：

[1] IBM Research Laboratory, San José

来源：

POLYMER | 1979年 / 20卷 / 11期

关键词：

D O I：

10.1016/0032-3861(79)90268-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Theories of rubber elasticity are reviewed and compared. Principal differences centre on the connection between the locations of network junctions and the macroscopic strain. Constraints on junctions imposed by surrounding chains have been postulated to be responsible for departures of experiments from the theory for idealized 'phantom' networks. Experimental evidence in support of theory developed using this hypothesis is discussed. © 1979.

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页码：1317 / 1320

页数：4

相关论文

共 36 条

[1] MODEL POLYURETHANE NETWORKS [J].

ALLEN, G ;

EGERTON, PL ;

WALSH, DJ .

POLYMER, 1976, 17 (01) :65-71

[2]

ALLEN G, 1974, FARADAY DISCUSS, V57, P19

[3] RUBBER ELASTICITY OF WELL-CHARACTERIZED POLYBUTADIENE NETWORKS [J].

DOSSIN, LM ;

GRAESSLEY, WW .

MACROMOLECULES, 1979, 12 (01) :123-130

[4]

DUISER JA, 1965, PHYSICS NONCRYSTALLI, P376

[5] THEORY OF ELASTICITY OF POLYMER NETWORKS .2. EFFECT OF GEOMETRIC CONSTRAINTS ON JUNCTIONS [J].

ERMAN, B ;

FLORY, PJ .

JOURNAL OF CHEMICAL PHYSICS, 1978, 68 (12) :5363-5369

[6] RUBBER ELASTICITY IN RANGE OF SMALL UNIAXIAL TENSIONS AND COMPRESSIONS - RESULTS FOR POLY(DIMETHYLSILOXANE) [J].

ERMAN, B ;

FLORY, PJ .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1978, 16 (06) :1115-1121

[7]

FALENDER JR, J CHEM PHYS

[8] THEORY OF ELASTICITY OF POLYMER NETWORKS - EFFECT OF LOCAL CONSTRAINTS ON JUNCTIONS [J].

FLORY, PJ .

JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (12) :5720-5729

[9] ELASTIC FREE-ENERGY OF DILATION OF A NETWORK [J].

FLORY, PJ .

MACROMOLECULES, 1979, 12 (01) :119-122

[10] STATISTICAL THERMODYNAMICS OF RANDOM NETWORKS [J].

FLORY, PJ .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1976, 351 (1666) :351-380

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