THE REACTION OF OH WITH CH4

被引：55

作者：

Margitan, J. J. ^{[1
]}

Kaufman, F. ^{[1
]}

Anderson, J. G. ^{[2
]}

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

[2] Univ Pittsburgh, Dept Phys, Pittsburgh, PA 15260 USA

来源：

GEOPHYSICAL RESEARCH LETTERS | 1974年 / 1卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1029/GL001i002p00080

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

The reaction of OH radicals with CH4 has been investigated over the temperature range 290-440 degrees K in a flow system with UV resonance fluorescence detection of OH. Its rate constant can be represented in Arrhenius form as k(1) = 3.83 x 10(-12) exp(-3660 (cal/mole)/RT) cm(3) sec(-1). This result is compared with the results of other experimenters and is used to calculate stratospheric destruction rates of methane.

引用

页码：80 / +

页数：2

共 12 条

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