PREPARATION AND CHARACTERIZATION OF HEXAALUMINATE-BASED MATERIALS FOR CATALYTIC COMBUSTION

被引:166
作者
GROPPI, G
BELLOTTO, M
CRISTIANI, C
FORZATTI, P
VILLA, PL
机构
[1] POLITECN MILAN,DIPARTIMENTO CHIM IND & INGN CHIM G NATTA,I-20133 MILAN,ITALY
[2] CISE SPA,MILAN,ITALY
关键词
BARIUM HEXAALUMINATE; CATALYST PREPARATION (PRECIPITATION); METHANE COMBUSTION;
D O I
10.1016/0926-860X(93)85092-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple preparation method for barium hexaaluminate-based catalysts to be used in catalytic combustion is described. Morphological and physico-chemical characterization data are given for Ba-Al-O (with Ba/Al=1/12) and for Ba-Mn-Al-O (with Ba/Mn/Al= 1/0.5/11.5; 1/1/11; 1/2/10) samples calcined at different temperatures. The preparation method here proposed provides stable materials with a surface area of 15 m(2)/g after calcination at 1400 degrees C. The structural and morphological properties, ae well as the results of activity tests in methane combustion, compare well with those reported in the literature for samples with the same composition and prepared according to a more complex preparation route.
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页码:101 / 108
页数:8
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