PERTURBATION OF OUT-OF-PLANE HYDROGEN-BONDING ON CARBOXYLATO GEOMETRY - STRUCTURE OF [ZN(BPY)2(MECO2)](CLO4).H2O

被引：15

作者：

CHEN, XM ^{[1
]}

XU, ZT ^{[1
]}

MAK, TCW ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG

来源：

POLYHEDRON | 1994年 / 13卷 / 24期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0277-5387(00)83115-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mixed-ligand monomeric complex [Zn(bpy)2(MeCO2)](ClO4).H2O (bpy = 2,2'-bipyridine) has been prepared and characterized by X-ray crystallography. The zinc(II) atom is surrounded in a highly distorted octahedral N4O2 environment with Zn-N bonds at 2.121(5)-2.131(4) angstrom and Zn-O bonds at 2.155(4)-2.246(4) angstrom. The acetato group forms an unusual out-of-plane hydrogen bond with the lattice water molecule.

引用

页码：3329 / 3332

页数：4

共 13 条

[1]

CHEN XM, 1991, INORG CHIM ACTA, V182, P139

[2] PREPARATION AND CRYSTAL-STRUCTURES OF BIS(O-PHENANTHROLINE)(ACETATO)ZINC(II) PERCHLORATE AND BIS(2,2'-BIPYRIDINE)(PYRIDINIOACETATO)ZINC(II) DIPERCHLORATE [J].