OXIDATION OF NITRIC OXIDE IN PRESENCE OF ULTRAVIOLET LIGHT AND HYDROCARBONS

被引：12

作者：

BUFALINI, JJ

ALTSHULL.AP

机构：

[1] U. S. Department of Health, Education, and Welfare, National Air Pollution Control Administration, Cincinnati, Ohio 45226

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1969年 / 3卷 / 05期

关键词：

D O I：

10.1021/es60028a009

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The oxidation of nitric oxide has been investigated in the presence of 2.3-dimethyl-2-butene, 1-butene, 1,3,5-trimethylbenzene, and n-butane. Nitrogen dioxide dosage curves are shown as a function of HC/NOx. ratios with NOx kept constant. The NO2 dosage increases very quickly with increasing concentrations of 2,3-dimethyl-2-butene and 1,3,5-trimethvlbenzene. Greater concentrations of 1-butene and n-butane are required to obtain similar increases in NO2 dosage. Oxidant was observed only after maximum dosage had been achieved. No oxidant was observed for the N-butane-NOx system under the conditions employed in this study. Neither the rate of oxidation of nitric oxide nor the rate of reaction of the hydrocarbon increased when water vapor was increased from 1.1 to 11 mm. © 1969, American Chemical Society. All rights reserved.

引用

页码：469 / &

共 20 条

[1]

ALTSHULLER AP, 1964, AIR WATER POLLUT, V8, P611

[2]

ALTSHULLER AP, 1963, AIR WATER POLLUT, V7, P787

[3]

ALTSHULLER AP, 1968, 61 ANN M AIR POLL CO

[4]

ALTSHULLER AP, 1967, SCIENCE, V150, P1161

[5]

ALTSHULLER AP, 1965, PHOTOCHEM PHOTOBIOL, V4, P97

[6]

[Anonymous], SCI TECHNOL HUM VAL, V46, P696, DOI [10.1021/es2030438, DOI 10.1021/ES2030438]

[7]

BODENSTEIN M, 1918, Z ANGEW CHEM, V31, P145

[8] NITROGEN - FORMATION BY PHOTOOXIDATION OF ETHYLENE IN PRESENCE OF ITS OXIDES [J].

BUFALINI, JJ ;

PURCELL, JC .

SCIENCE, 1965, 150 (3700) :1161-&

[9]

BUFALINI JJ, 1965, AIR WATER POLLUT, V9, P123

[10]

CADLE RD, 1961, CHEMICAL REACTION ED, P51

← 1 2 →