Theoretical treatment of solvent effects on the electronic spectra of polar organic dye molecules

被引：22

作者：

Kuhn, H. ^{[1
]}

Schweig, A. ^{[1
]}

机构：

[1] Univ Marburg, Inst Phys Chem, D-35032 Marburg, Germany

来源：

CHEMICAL PHYSICS LETTERS | 1967年 / 1卷 / 06期

关键词：

D O I：

10.1016/0009-2614(67)85021-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dye molecule in a saturated hydrocarbon solvent (instead of the vacuum) is taken as reference state; the sigma-electrons of solute and solvent are treated as a continuous medium of dielectric constant epsilon(0) = 2. The pi-electrons of the solute are assumed to be immersed in this medium. Solvent shifts of absorption and fluorescence are calculated from known ground and excited state dipole moments and polarizabilities of solute and dielectric constant and refractive index of solvent.

引用

页码：255 / 258

页数：4

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