FORMATION OF LI+ AND CD2+ CATENATES, A REACTION WITH A NEGATIVE ENTHALPY OF ACTIVATION

被引：15

作者：

ALBRECHTGARY, AM ^{[1
]}

DIETRICHBUCHECKER, C ^{[1
]}

SAAD, Z ^{[1
]}

SAUVAGE, JP ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST CHIM,CHIM ORGANOMINERALE LAB,CNRS,URA 422,F-67070 STRASBOURG,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000280

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of formation of Li+ and Cd2+ catenates involves two kinetically observable steps; the slower one consists of two processes and has a negative activation enthalpy, supporting a preequilibrium between two complexed species in the mononuclear rearrangement leading to the catenate structure.

引用

页码：280 / 282

页数：3

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