BARRIERS TO ENERGY MIGRATION IN MIXED-LIGAND ZINC(II) COMPLEXES

被引：12

作者：

BURT, JA ^{[1
]}

CROSBY, GA ^{[1
]}

机构：

[1] WASHINGTON STATE UNIV,DEPT CHEM,PULLMAN,WA 99164

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 220卷 / 06期

关键词：

D O I：

10.1016/0009-2614(94)00206-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spectroscopic investigations of Zn(4-Cl-PhS)2(dmphen) (4-Cl-PhS=anion of 4-chlorobenzenethiol; dampen=2,9-dimethyl- 1, 10-phenanthroline) in the p2(1)/N and p2(1)/C crystal phases and in polymethylmethacrylate (PMMA) are reported. The results demonstrate the existence of an intramolecular barrier to energy migration between 3pipi* and ligand-to-ligand charge-transfer levels.

引用

页码：493 / 496

页数：4

共 6 条

[1]

BURT JA, IN PRESS

[2] REDISTRIBUTION OF EXCITATION-ENERGY BETWEEN NONEQUILIBRATED ELECTRONIC EXCITED-LEVELS OF ZINC(II) COMPLEXES [J].