ENDOCYANONORCARADIENE AND EXO-7-CYANONORCARADIENE ENDOPEROXIDES .79. SYNTHESIS, CHARACTERIZATION, AND TRANSFORMATIONS

被引：26

作者：

ADAM, W

BALCI, M

机构：

[1] Department of Chemistry, University of Puerto Rico, Rio Piedras

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 07期

关键词：

D O I：

10.1021/jo01321a046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compounds, 3a and 3b, were prepared by singlet oxygenation of the corresponding norcaradiene derivatives 2a and 2b, characterized by diimide reduction as the respective norcarane endoperoxides 4a and 4b, and transformed into their respective diepoxides 5a and 5b on heating and ene epoxides 6a and 6b on deoxvgenation with triphenylphosphine. Copyright. © 1979, American Chemical Society. All rights reserved.

引用

页码：1189 / 1190

页数：2

共 8 条

[1] PROSTANOID ENDOPEROXIDE MODEL COMPOUNDS - 2,3-DIOXABICYCLO[2.2.1]HEPTANE VIA SELECTIVE DIIMIDE REDUCTION
ADAM, W
EGGELTE, HJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (24) : 3987 - 3988
[2] SENSITIZED PHOTO-OXIDATION OF CYCLOHEPTATRIENE (TROPILIDENE) - ISOLATION AND THERMAL-ISOMERIZATION OF (4-PI+2-PI) CYCLOADDUCT, 8,9-DIOXABICYCLO-[3.2.2]-2,6-NONADIENE, AND PREPARATION OF TROPONE
ASAO, T
YAGIHARA, M
KITAHARA, Y
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (07) : 2131 - 2135
[3] GUNTHER H, 1970, TETRAHEDRON LETT, P5173
[4] HOFFMANN R, 1970, TETRAHEDRON LETT, P2907
[5] KABUTO C, 1973, ANGEW CHEM, V85, P860
[6] PHOTOOXIDATION OF CYCLOHEPTATRIENES SENSITIZED BY ALPHA-DICARBONYL COMPOUNDS - OCCURRENCE OF DIOXYGENATION REACTION
MORI, A
TAKESHITA, H
[J]. CHEMISTRY LETTERS, 1978, (04) : 395 - 396
[7] ODA M, 1969, TETRAHEDRON LETT, P3295
[8] DIRECT OBSERVATION OF BUCHNERS ACID USING C-13 AND H-1 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY
WEHNER, R
GUNTHER, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (04) : 923 - 924

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