FORMATION OF A TRANS-1,2,4,5-TETRAPHOSPHATRICYCLO-[3.1.0.0/2,4]HEXANE BY [2+2]-CYCLODIMERIZATION OF A 3H-DIPHOSPHIRENE

被引：22

作者：

NIECKE, E

STREUBEL, R

NIEGER, M

机构：

[1] Anorganisch-Chemisches Institut, Universität Bonn, W-5300 1

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1002/anie.199100901

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of a 3H-diphosphirene by reaction of per(trimethylsilyl)-substituted 1,2-diphospha-2-propene with hexachloroethane was the goal. Although it was not possible to isolate this unknown isomer, its formation as an intermediate was demonstrated by further reaction to give the tricyclic dimer 1 with a planar P4 unit.

引用

页码：90 / 91

页数：2

共 20 条

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