ELECTROCHEMICAL TRANSFORMATION OF ALKYLIDENEMALONATES INTO 2-ALKYL-3,3-DIMETHOXYALKANE-1,1-DICARBOXYLATES VIA REARRANGEMENT

被引：10

作者：

NIKISHIN, GI

ELINSON, MN

FEDUCOVICH, SK

机构：

[1] N.D. Zelinsky Institute of Organic Chemistry, U.S.S.R. Academy of Sciences, Moscow

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 06期

关键词：

D O I：

10.1016/S0040-4039(00)74890-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Alkylidenemalonates capable of migration of a double bond being electrolyzed in methanol in the presence of alkali metal halides in an undivided cell are transformed into 2-alkyl-3,3-dimethoxyalkane-1,1-dicarboxylates, acidification of which leads to 2-alkyl-3-oxoalkane-1,1-dicarboxylates.

引用

页码：799 / 800

页数：2

共 5 条

[1]

[Anonymous], 1986, ANGEW CHEM, V98, P681

[2]

ELECTROCHEMICAL SELECTIVE TRIMERIZATION OF MALONIC ESTERS INTO ESTERS OF PROPANE-1,1,2,2,3,3-HEXACARBOXYLIC ACID IN THE PRESENCE OF HYDROBROMIC ACID SALTS [J].