SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [AU9AG4CL4(PMEPH2)8][C2B9H12]BULLET-H2O-BULLET-0.5CH2CL2 - THE 1ST EXAMPLE OF AN ICOSAHEDRAL SILVER GOLD CLUSTER

被引：30

作者：

COPLEY, RCB ^{[1
]}

MINGOS, DMP ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 10期

关键词：

D O I：

10.1039/dt9920001755

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [Au9Ag4Cl4(PMePh2)8] [C2B9H12].H2O.0.5CH2Cl2 has been synthesised in high yield from [Au11(PMePh2)10]3+ and [Ag(PMePh2)Cl] in CH2Cl2 and its centred icosahedral geometry has been confirmed by single-crystal X-ray diffraction measurements.

引用

页码：1755 / 1756

页数：2

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