PREPARATION AND X-RAY STRUCTURE OF A NOVEL DELOCALIZED DIPHOSPHAZENE COMPLEX - [OS3(CO)11((CF3)2P=N=PPH3)]

被引：7

作者：

ANG, HG ^{[1
]}

CAI, YM ^{[1
]}

KWIK, WL ^{[1
]}

LEONG, WK ^{[1
]}

TOCHER, DA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 08期

关键词：

D O I：

10.1016/S0277-5387(00)86124-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound 1, obtained from the reaction of [Os3(CO)11(CH3CN)] with (CF3)2P-N=PPh3, has been characterized by spectroscopic and X-ray structural analyses. The osmium atoms form an approximate isosceles triangle with an equatorial site being taken up by the diphosphazene ligand. The P-N-P moiety is nearly linear and the two P-N bonds are equivalent.

引用

页码：881 / 882

页数：2

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