PT-195 NMR-STUDY OF (ETA-5-CYCLOPENTADIENYL)TRIALKYLPLATINUM(IV) COMPLEXES

被引：12

作者：

BOARDMAN, LD

NEWMARK, RA

机构：

[1] Consumer Sector Research Laboratory, 3M Center, St. Paul, Minnesota

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1992年 / 30卷 / 06期

关键词：

PLATINUM COMPLEXES; PT-195; NMR; H-1; C-13;

D O I：

10.1002/mrc.1260300605

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pt-195 NMR data are reported for a series of (eta-5-cyclopentadienyl)trialkylplatinum(IV) complexes. Chemical shift differences are rationalized primarily on the basis of substituent electronic properties. Changes in solvent produce relatively modest changes in chemical shift, and the dependence of the chemical shift on temperature and concentration is sufficiently strong to warrant control of these variables for comparative measurements. An improved synthesis of [IPtMe3]4 is also described.

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页码：481 / 489

页数：9

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