ON THE WAY TO DELOCALIZED ORGANOMETALLIC POLYMERS - TRIPLE-DECKER AND QUADRUPLE-DECKER PENTALENE COMPLEXES OF IRON AND COBALT

被引：55

作者：

OELCKERS, B ^{[1
]}

CHAVEZ, I ^{[1
]}

MANRIQUEZ, JM ^{[1
]}

ROMAN, E ^{[1
]}

机构：

[1] CTR INVEST MINERAS & MET, SANTIAGO, CHILE

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 09期

关键词：

D O I：

10.1021/om00033a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new class of triple- and quadruple-decker complexes of iron and cobalt derived from pentalene was prepared. The triple-deckers are prepared through the reaction of the bis(hydropentalenyl)iron monolithium salt 2 with Cp*M(acac) (M = Fe, Co). Two types of iron quadruple-deckers were also prepared, the first through the reaction of 2 with Fe (acac)2, and the second through there action of 3 with n-butyllithium followed by Cp*Fe-(acac).

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页码：3396 / 3397

页数：2

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