HEXASPIRO[2.4.2.4.2.4.2.4.2.4.2.4]DOTETRACONTA-4,6,11,13,18,20,25,27,32,34,39,41-DODECAYNE - AN EXPLODING [6]ROTANE

被引：44

作者：

DEMEIJERE, A

KOZHUSHKOV, S

PULS, C

HAUMANN, T

BOESE, R

COONEY, MJ

SCOTT, LT

机构：

[1] UNIV GOTTINGEN,INST ORGAN CHEM,D-37077 GOTTINGEN,GERMANY

[2] BOSTON COLL,MERKERT CHEM CTR,DEPT CHEM,CHESTNUT HILL,MA 02167

[3] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,W-4300 ESSEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 08期

关键词：

D O I：

10.1002/anie.199408691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidative coupling of the acyclic trimer of 1,1 ‐di‐ethynylcyclopropane gives title compound 1 as the main product. X‐ray structural analysis of 1 shows that the spirocyclopropane and adjacent butadiyne units have a distinct electronic interaction. A dehydrononamer (C63H36) was also isolated. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：869 / 871

页数：3

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