PIGMENTS OF FUNGI .16. SYNTHESIS OF METHYL (R)-(+)-TETRAHYDRO-2-METHYL-5-OXO-2-FURANACETATE AND ITS (S)-(-)-ANTIPODE, CHIROPTICAL REFERENCES FOR DETERMINATION OF THE ABSOLUTE STEREOCHEMISTRY OF FUNGAL PRE-ANTHRAQUINONES

被引：23

作者：

GILL, M

SMRDEL, AF

机构：

[1] Department of Organic Chemistry, University of Melbourne, Parkville

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86350-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The (R)- and (S)-butanolides 7 and 9 are synthesized via asymmetric epoxidation from geraniol; the (R)-butanolide 7 is also obtained from (S)- citramalic acid. The butanolides 7 and 9 are valuable reference compounds for the determination of absolute stereochemistry in fungal and plant pre-anthraquinones. © 1990.

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页码：453 / 464

页数：12

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