ENANTIOSELECTIVE PREPARATION OF 1,3-CYCLOHEXADIENE AND 1,4-CYCLOHEPTADIENE DERIVATIVES - SYNTHESIS OF (PLUS)-DICTYOPTERENE C'

被引：6

作者：

ASAOKA, M

KOBAYASHI, K

TAKEI, H

机构：

[1] Department of Life Chemistry, Tokyo Institute of Technology, Midori-ku

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 04期

关键词：

D O I：

10.1246/bcsj.67.1141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Starting from optically active 5-trimethylsilyl-2-cyclohexen-1-one derivatives, the title dienes were synthesized by using silicon-mediated 1,4-elimination as a key step. A straightforward synthesis of the unnatural enantiomer of (-)-dictyopterene C' utilizing the method was also carried out.

引用

页码：1141 / 1146

页数：6

共 30 条

[1] CONSTRUCTION OF CHIRAL QUARTERNARY CARBON CENTERS USING 3-SUBSTITUTED 5-TRIMETHYLSILYL-2-CYCLOHEXENONES - SYNTHESIS OF (+)-ALPHA-CUPARENONE [J].