CHEMISTRY OF ALIPHATIC UNCONJUGATED NITRAMINES .3. THERMAL, ELECTROPHILIC, AND NUCLEOPHILIC REACTIONS

被引：16

作者：

STALS, J

机构：

[1] Australian Defence Scientific Service, Department of Supply, Defence Standards Laboratories, Ascot Vale, VIC, 3032

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 12期

关键词：

D O I：

10.1071/CH9692515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The VESCF(BJ)-MO electronic bond energies, charge distributions, bond orders, free valencies, and frontier orbital charges, when used as reactivity indices, provide a surprisingly good account of the thermal decomposition and of the electrophilic and nucleophilic substitution reactions of nitramide and primary and secondary aliphatic nitramines. A good account of the chemistry of RDX and HMX is also given by the calculated parameters for s- and as-N, N-dimethylnitramines. © 1969, CSIRO. All rights reserved.

引用

页码：2515 / &

共 33 条

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