CHIRAL SYNTHESIS OF Z-2-BUTYLIDENECYCLOHEXAN-1-OL AND Z-2-BUTYLIDENECYCLOHEXAN-1-YL PHENYLSULFIDE FROM OPTICALLY-ACTIVE PHOSPHINE OXIDES

被引：39

作者：

HARMAT, NJS ^{[1
]}

WARREN, S ^{[1
]}

机构：

[1] UNIV CAMBRIDGE, CHEM LAB, CAMBRIDGE CB2 1EW, ENGLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)94688-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active butyl(ortho-methoxyphenyl)phenylphosphine oxide is used to create three new chiral carbon atoms as a carbon framework is built up by stereoselective electrophilic attack on a cyclic allylic phosphine oxide. Elimination of the chiral auxiliary in a Horner-Wittig reaction gives the title compounds. © 1990.

引用

页码：2743 / 2746

页数：4

共 25 条

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