MECHANISM OF THE GROUND-STATE REVERSE PROTON-TRANSFER OF 2-(2-HYDROXYPHENYL)BENZOTHIAZOLE

被引：115

作者：

BREWER, WE ^{[1
]}

MARTINEZ, ML ^{[1
]}

CHOU, PT ^{[1
]}

机构：

[1] UNIV SO ALABAMA,DEPT CHEM,MOBILE,AL 36688

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 05期

关键词：

D O I：

10.1021/j100368a036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ground-state reverse proton transfer of 2-(2-hydroxyphenyl)benzothiazole is investigated by transient absorption and two-step laser excitation experiments. The observed dynamics suggest the existence of two long-lived (> microsecond time scale) phototautomers in the ground state. These two species are ascribed to the twisted and trans conformers, whereas the cis conformer is concluded to undergo a rapid (≪50 ns) reverse proton transfer in the ground state. © 1990 American Chemical Society.

引用

页码：1915 / 1918

页数：4

共 20 条

[1] INTRAMOLECULAR PROTON-TRANSFER AND EXCITED-STATE RELAXATION IN 2-(2-HYDROXYPHENYL)BENZOTHIAZOLE
BARBARA, PF
BRUS, LE
RENTZEPIS, PM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (17) : 5631 - 5635
[2] A COMPREHENSIVE INVESTIGATION OF THE PHOTOPHYSICS AND PHOTOCHEMISTRY OF SALICYLIDENEANILINE AND DERIVATIVES OF PHENYLBENZOTHIAZOLE INCLUDING SOLVENT EFFECTS
BECKER, RS
LENOBLE, C
ZEIN, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (13) : 3509 - 3517
[3] PHOTOPHYSICS AND PHOTOCHEMISTRY OF THE NITRO-DERIVATIVES OF SALICYLIDENEANILINE AND 2-(2'-HYDROXYPHENYL)BENZOTHIAZOLE AND SOLVENT EFFECTS
BECKER, RS
LENOBLE, C
ZEIN, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (13) : 3517 - 3524
[4] BIRKS JB, 1970, PHOTOPHYSICS AROMATI, P109
[5] DYNAMICS OF THE TRIPLET-STATE AND THE REVERSE PROTON-TRANSFER OF 3-HYDROXYFLAVONE
BREWER, WE
STUDER, SL
STANDIFORD, M
CHOU, PT
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (16) : 6088 - 6094
[6] TOPOCHEMISTRY .24. LUMINESCENCE PROPERTIES OF N-SALICYLIDENEANILINE AND RELATED ANILS IN SOLUTION
COHEN, MD
FLAVIAN, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1967, (04): : 317 - &
[7] EXCITED-STATE INTRAMOLECULAR PROTON-TRANSFER AND VIBRATIONAL-RELAXATION IN 2-(2-HYDROXYPHENYL)BENZOTHIAZOLE
DING, K
COURTNEY, SJ
STRANDJORD, AJ
FLOM, S
FRIEDRICH, D
BARBARA, PF
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (07) : 1184 - 1188
[8] VISIBLE AND INFRARED-SPECTROSCOPY OF INTRAMOLECULAR PROTON-TRANSFER USING PICOSECOND LASER-PULSES
ELSAESSER, T
KAISER, W
[J]. CHEMICAL PHYSICS LETTERS, 1986, 128 (03) : 231 - 237
[9] EXCITED-STATE PROTON-TRANSFER IN 2-(2'-HYDROXYPHENYL)BENZOTHIAZOLE - TRANSIENT ELECTRONIC ABSORPTION MEASURED ON THE PICOSECOND TIME SCALE
ELSAESSER, T
SCHMETZER, B
LIPP, M
BAUERLE, RJ
[J]. CHEMICAL PHYSICS LETTERS, 1988, 148 (2-3) : 112 - 118
[10] EXCITED-STATE PROTON-TRANSFER IN 2-(2'-HYDROXYPHENYL)BENZOTHIAZOLE - FORMATION OF THE ANION IN POLAR-SOLVENTS
ELSAESSER, T
SCHMETZER, B
[J]. CHEMICAL PHYSICS LETTERS, 1987, 140 (03) : 293 - 299

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