CONFORMATIONAL DIFFERENCES IN DIOXOURANIUM(VI) COORDINATION-COMPOUNDS - CRYSTAL-STRUCTURE OF THE CHLOROFORM ADDUCT OF N,N'-BIS-SALICYLIDENE-1,5-DIAMINO-3-OXAPENTANE-DIOXOURANIUM(VI)

被引：11

作者：

BOMBIERI, G ^{[1
]}

FORSELLINI, E ^{[1
]}

BENETOLLO, F ^{[1
]}

FENTON, DE ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 10期

关键词：

D O I：

10.1016/0022-1902(79)80207-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound (UO2-saloden·CHCl3) crystallizes in an orthorhombic system, space group Cmc21 with a = 16.938(6), b = 12.440(5) and c = 10.662(4) A ̊, Z = 4. The coordination geometry of the uranium atom is bipyramidal pentagonal with the ligand pentadentate in the equatorial plane of the uranyl ion. The chloroform molecule does not interact directly with the ligand. The IR spectral data are also discussed. © 1979.

引用

页码：1437 / 1441

页数：5

共 10 条

[1] CRYSTAL AND MOLECULAR-STRUCTURE OF N,N'-BISSALICYLIDENE-1,5-DIAMINO-3-AZAPENTANE-DIOXOURANIUM(VI)
AKHTAR, MN
SMITH, AJ
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, B 29 (FEB15): : 275 - 279
[2] BAKER EN, 1970, J CHEM SOC A, P406, DOI 10.1039/j19700000406
[3] CONFORMATIONAL ISOMERS OF N,N'-BIS-SALICYLIDENE-1,5-DIAMINO-3-OXAPENTANE-DIOXOURANIUM(VI) - 2 EXAMPLES OF COMPOUNDS CONTAINING BENT URANYL GROUPS
BROCK, AM
COOK, DH
FENTON, DE
BOMBIERI, G
FORSELLINI, E
BENETOLLO, F
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1978, 40 (08): : 1551 - 1559
[4] RELATIVISTIC CALCULATION OF ANOMALOUS SCATTERING FACTORS FOR X-RAYS
CROMER, DT
LIBERMAN, D
[J]. JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (05) : 1891 - &
[5] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS
CROMER, DT
MANN, JB
[J]. ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 : 321 - &
[6] MCKENZIE ED, 1975, INORG CHIM ACTA, V10, P41
[7] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION
NORTH, ACT
PHILLIPS, DC
MATHEWS, FS
[J]. ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 : 351 - &
[8] SHELDRICK G, 1976, SHELX76 U CAMBR COMP
[9] COHERENT X-RAY SCATTERING FOR HYDROGEN ATOM IN HYDROGEN MOLECULE
STEWART, RF
DAVIDSON, ER
SIMPSON, WT
[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (09) : 3175 - &
[10] INT TABLES CRYST, V4, P101

← 1 →