TRIS-PYRAZOLYL-BORATE DIHYDROGEN COMPLEXES OF RUTHENIUM

被引：41

作者：

HALCROW, MA

CHAUDRET, B

TROFIMENKO, S

机构：

[1] UNIV PAUL SABATIER,CHIM COORDINAT LAB,CNRS,UP 8241 LIEE CONVENT,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

[2] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

[3] DU PONT CO,POLYMERS,RES & DEV,EXPT STN,WILMINGTON,DE 19880

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 05期

关键词：

D O I：

10.1039/c39930000465

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [Ru(PCY3)2(H2)HI] with K(tpb) or Tl(tdmpb) affords the molecular hydrogen complexes [Ru(eta3-L)(PCY3)(H2)H] (L = tpb or tdmpb), via the intermediates trans-[RU(eta2-L)(PCY3)2(H2)H]; protonation of [Ru(tpb)(PCY3)(H2)H] with HBF4.Et2O leads to the cationic aquo-dihydrogen complex [Ru(tpb)(PCY3)(OH2)(H2)]BF4.

引用

页码：465 / 467

页数：3

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