EXTENDED 8,14-SECOHOPANES IN SOME SEEP OILS FROM PAKISTAN

被引:26
作者
FAZEELAT, T
ALEXANDER, R
KAGI, RI
机构
[1] Centre for Petroleum and Environmental Organic Geochemistry, School of Applied Chemistry, Curtin University of Technology, Perth, WA 6001
关键词
EXTENDED 8,14-SECOHOPANES; CRUDE OIL; PETROLEUM; OIL SEEPS; PAKISTAN;
D O I
10.1016/0146-6380(94)90189-9
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
An alkane fraction isolated from Pakistani oil seep samples using liquid chromatography on US-Y molecular sieves has been shown to contain six pseudohomologous series of tetracyclic compounds that have mass spectral characteristics of 8,14-secohopanes with carbon numbers extending to 35. This is the first report of extended 8,14-secohopanes in a crude oil, although extended 8,14-secohopanes with up to 32 carbon atoms have previously been reported from a Chinese coal of Jurassic age. The Kovats indices of these extended 8,14-secohopanes are reported from measurements using capillary gas chromatography columns with nonpolar and polar stationary phases.
引用
收藏
页码:257 / 264
页数:8
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