CALCIUM-OXIDE AS A CATALYST FOR THE ISOMERIZATION OF 5-VINYLBICYCLO[2.2.1]HEPT-2-ENE TO 5-ETHYLIDENEBICYCLO[2.2.1]HEPT-2-ENE IN THE LIQUID-PHASE

被引：11

作者：

BABA, T

ENDOU, T

HANDA, H

ONO, Y

机构：

[1] Department of Chemical Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152, Ookayama

来源：

APPLIED CATALYSIS A-GENERAL | 1993年 / 97卷 / 01期

关键词：

CALCIUM OXIDE; 5-ETHYLIDENEBICYCLO[2.2.1]HEPT-2-ENE; ISOMERIZATION; LIQUID PHASE; SOLID BASE; 5-VINYLBICYCLO[2.2.1]HEPT-2-ENE;

D O I：

10.1016/0926-860X(93)80061-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Calcium oxide prepared by decomposing CaCO3 in vacuo shows a very high catalytic activity for the isomerization of 5-vinylbicyclo[2.2.1]hept-2-ene (VBH) to 5-ethylidenebicyclo[2.2.1]hept-2-ene (ENB), the yield of which reached 99.8% at 273 K in 10 min.

引用

页码：L19 / L23

页数：5

共 9 条

[1]

HATTORI H, 1985, STUDIES SURFACE SCI, V21, P319

[2]

MIYZOYAN ZA, 1974, DOKL AKAD NAUK SSSR, V30, P28

[3]

PINES H, 1977, BASE CATALYSED REACT, pCH2

[4]

PLATE AF, 1960, J GEN CHEM USSR, V30, P3902

[5]

RANNEVA YI, 1974, J ORG CHEM SSSR, V10, P2119

[6] PREPARATION OF NEW SOLID SUPERBASE AND ITS CATALYTIC ACTIVITY [J].

SUZUKAMO, G ;

FUKAO, M ;

MINOBE, M .

CHEMISTRY LETTERS, 1987, (04) :585-588

[7]

SUZUKAMO G, 1989, NEW SOLID BASES, P405

[8]

Tanabe K, 1985, STUDIES SURFACE SCI, P1, DOI DOI 10.1016/30167-2991(09)60151-8

[9]

TANABE K, 1989, STUDIES SURFACE SCI, V51, P1, DOI DOI 10.1016/S0167-2991(08)61044-7

← 1 →