EQUATIONS OF STATE OF ADSORBATES WITH FRACTAL DIMENSION

被引：26

作者：

KELLER, JU

机构：

[1] Institute für Fluid- und Thermodynamik, Universität Siegen

来源：

PHYSICA A | 1990年 / 166卷 / 02期

关键词：

D O I：

10.1016/0378-4371(90)90011-G

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Isotherms and enthalpies of multicomponent adsorbates with load-dependent adsorption energies, being formed on adsorbates with fractal surfaces (2≤D≤3) and being in equilibrium with either real fluid- or ideal gas-adsorptives, are given. The functions proposed are solutions of a set of Maxwell's relations and other thermodynamic consistency conditions. Special cases of the general expressions given are discussed to a certain extent, among them generalizations of the Langmuir-Freundlich and the BET adsorption isotherms. © 1990.

引用

页码：180 / 192

页数：13

共 26 条

[1]

BUNDE A, 1986, ADV SOLID STATE PHYS, P113

[2]

Farin D., 1988, CHARACTERIZATION POR, P421

[3]

FINDENEGG GH, 1987, 1986 P ENG F C FUND

[4]

GREGG SJ, 1982, ADSORPTION SURFACE A, P67