VIBRATIONAL ANALYSIS OF (SCN)2 AND THE TRANSIENT (SCN)2-

被引：25

作者：

JENSEN, NH ^{[1
]}

WILBRANDT, R ^{[1
]}

PAGSBERG, P ^{[1
]}

HESTER, RE ^{[1
]}

ERNSTBRUNNER, E ^{[1
]}

机构：

[1] UNIV YORK,HESLINGTON YO1 5DD,YORKSHIRE,ENGLAND

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 71卷 / 08期

关键词：

D O I：

10.1063/1.438774

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational spectra of thiocyanogen and the transient radical anion (SCN)2- are interpreted in detail through molecular orbital and normal coordinate calculations. The results support the assignment of (SCN)2- to the anion of thiocyanogen and indicate a substantial weakening of the S-S and C≡N bonds in going from the parent molecule to its radical anion. © 1979 American Institute of Physics.

引用

页码：3326 / 3329

页数：4

共 24 条

[1] SCF-MO-CNDO STUDY OF EQUILIBRIUM GEOMETRIES, FORCE CONSTANTS, AND BONDING ENERGIES - CNDO/BW .1. PARAMETERIZATION [J].

BOYD, RJ ;

WHITEHEA.MA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (01) :73-&

[2]

BRIDOUX M, 1978, 6TH P INT C RAM SPEC, P381

[3] RESONANCE RAMAN KINETIC SPECTROSCOPY OF BACTERIORHODOPSIN ON MICROSECOND TIME SCALE [J].

CAMPION, A ;

ELSAYED, MA ;

TERNER, J .

BIOPHYSICAL JOURNAL, 1977, 20 (03) :369-375

[4]

ERNSTBRUNNER E, 1978, J CHEM SOC PERK T 2, V74, P177

[5] FREE-RADICAL STUDIES BY RESONANCE RAMAN-SPECTROSCOPY .2. DIAZABICYCLO-OCTANE RADICAL CATION [J].

ERNSTBRUNNER, EE ;

GIRLING, RB ;

GROSSMAN, WEL ;

HESTER, RE .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1978, 74 :501-508

[6] FREE-RADICAL STUDIES BY RESONANCE RAMAN-SPECTROSCOPY .3. 4-NITROBENZOATE RADICAL DIANION [J].

ERNSTBRUNNER, EE ;

GIRLING, RB ;

HESTER, RE .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1978, 74 :1540-1549

[7] BEITRAGE ZUR CHEMIE DES SCHWEFELS .49. UBER DIE HOMOLOGE REIHE DER CYANSULFANE SN(CN)2 [J].

FEHER, F ;

WEBER, H .

CHEMISCHE BERICHTE-RECUEIL, 1958, 91 (03) :642-650

[8] VIBRATIONAL-SPECTRA AND FORCE CONSTANTS OF CHLORATE, BROMATE AND IODATE IONS IN AQUEOUS-SOLUTION [J].

GARDINER, DJ ;

GIRLING, RB ;

HESTER, RE .

JOURNAL OF MOLECULAR STRUCTURE, 1972, 13 (01) :105-+

[9]

HESTER RE, 1978, ADV INFRARED RAMAN S, V4, pCH1

[10] KINETIC RESONANCE RAMAN-SPECTROSCOPY - DYNAMICS OF DEPROTONATION OF SCHIFF-BASE OF BACTERIORHODOPSIN [J].

MARCUS, MA ;

LEWIS, A .

SCIENCE, 1977, 195 (4284) :1328-1330

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