STYRYLBENZODIAZINONES .3. CHROMOIONOPHORES AND FLUOROIONOPHORES DERIVED FROM MONOAZA-15-CROWN-5 - PHOTOPHYSICAL AND COMPLEXING PROPERTIES

被引：35

作者：

CAZAUX, L ^{[1
]}

FAHER, M ^{[1
]}

LOPEZ, A ^{[1
]}

PICARD, C ^{[1
]}

TISNES, P ^{[1
]}

机构：

[1] PHARMACOL & TOXICOL FONDAMENTALES LAB,CNRS,UPA 8221,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1994年 / 77卷 / 2-3期

关键词：

D O I：

10.1016/1010-6030(94)80046-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photophysical and complexing properties of two chromo- and fluoroionophores derived from the monoaza-15-crown-5 and styrylbenzodiazinones are studied by UV spectrophotometry and spectrofluorometry. Their comparison with those of BOZ-crown and DCM-crown analogous dyes shows the specificity of the benzodiazinone moiety on these properties. The occurrence of twisted intramolecular charge transfer states by internal rotation around the ArC-N bond and the effects of biological metallic ions are discussed.

引用

页码：217 / 225

页数：9

共 25 条

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