CRYSTAL-STRUCTURE OF A NEW CHIRAL PD(0)/DIPHOSPHINE COMPLEX AND ITS USE IN ENANTIOSELECTIVE ALLYLIC ALKYLATIONS

被引：32

作者：

BOLM, C

KAUFMANN, D

GESSLER, S

HARMS, K

机构：

[1] Fachbereich Chemie der Philipps-Universität Marburg, D-35032 Marburg, Hans-Meerwein-Straße

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 502卷 / 1-2期

关键词：

PALLADIUM(0) COMPLEX; ENANTIOSELECTIVE ALLYLIC SUBSTITUTION; ASYMMETRIC CATALYSIS;

D O I：

10.1016/0022-328X(95)05687-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the new chiral Pd(0) complex (R,R)-2 bearing two homochiral diphosphine ligands is reported. Its catalytic activity and enantioselectivity in allylic substitution reactions were investigated and the results compared to those obtained with various in-situ catalyst systems derived from [Pd(allyl)Cl](2) and diphosphine (R)-1.

引用

页码：47 / 52

页数：6

共 59 条

[1]

ANDRIANOV VG, 1976, J STRUCT CHEM, V17, P105

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

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