INTERFERENCE EFFECTS IN OPTICAL SPECTRUM OF LARGE MOLECULES

被引：63

作者：

JORTNER, J

MORRIS, GC

机构：

[1] Department of Chemistry, James Franck Institute, University of Chicago, Chicago

[2] Department of Chemistry, Tel-Aviv University

[3] Department of Chemistry, University of Queensland, St. Lucia

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 09期

关键词：

D O I：

10.1063/1.1672579

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Interference effects between intravalence and extravalence excitations in the optical spectrum of a large molecule are considered. The sharp antiresonances observed in the Rydberg spectrum of the naphthalene molecule are interpreted in terms of configuration interaction between zero-order Rydberg levels and an inhomogeneously broadened π→π* transition.

引用

页码：3689 / &

共 21 条

[1] ABSORPTION SPECTRA IN VACUUM ULTRAVIOLET AND IONIZATION POTENTIALS OF NAPHTHALENE AND NAPHTHALENE-D8 MOLECULES [J].