ABSOLUTE QUANTUM YIELD OF O D-1(2) IN THE PHOTOLYSIS OF OZONE IN THE HARTLEY BAND

被引:19
作者
KAJIMOTO, O [1 ]
CVETANOVIC, RJ [1 ]
机构
[1] NATL RES COUNCIL CANADA,DIV CHEM,OTTAWA,ONTARIO,CANADA
关键词
D O I
10.1002/kin.550110607
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The absolute quantum yield of O(1D2) in the photolysis of ozone in the Hartley band, between about 230 and 280 nm, has been determined using the isotopic exchange reaction between C16O2 and 18O(1D2). A value of 1.00 ± 0.05 has been obtained within a 95% confidence limit. A value of unity may therefore be accepted as the average quantum yield of O(1D2) atoms in the 230–280‐nm region within an uncertainty of only several percent. Copyright © 1979 John Wiley & Sons, Inc.
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页码:605 / 612
页数:8
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