P-NMR STUDY ON THE AG(TRIPHOS)X SERIES (TRIPHOS = 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE, X = ANION) - CRYSTAL AND MOLECULAR-STRUCTURE OF AG(TRIPHOS)I

被引：15

作者：

CAMALLI, M ^{[1
]}

CARUSO, F ^{[1
]}

机构：

[1] CNR,IST STRUTTURIST CHIM G GIACOMELLO,CP 10,I-00016 MONTEROTONDO,ITALY

来源：

INORGANICA CHIMICA ACTA | 1990年 / 169卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)80516-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The series of complexes Ag(triphos)X, triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane, X = I, Cl, CH3COO, NO3, ClO4, has been synthesized. P NMR data, in solution, show that anions with lower basicity are associated with higher chemical shifts and higher coupling constants. Only two complexes, X = NO3 and ClO4, have available 1J(107Ag31P), the other complexes are still dynamic at 193 K. The two coupling constants appear higher than expected for complexes of the type 'AgP3'. The crystalline species Ag(triphos)I is orthorhombic, space group Pna21, a = 20.534(6), b = 10.363(3), c = 17.724(4) Å, and isomorphous with other tetrahedral complexes of triphos (Ni(triphos)I, Ni(triphos)SO2). An analysis of complexes of triphos so far reported shows that Ag(triphos)I has the longest (MP) bond distance and the smallest (PMP) bond angle. © 1990.

引用

页码：189 / 194

页数：6

共 37 条

[1] STRUCTURAL STUDIES ON SILVER(I) COMPLEXES WITH 2,11-BIS((DIPHENYLPHOSPHINO)METHYL)BENZO[C]PHENANTHRENE (1) - [AG(1)CL], [AG(1)(SNCL3)], [AG(1)(NO3)], AND [AG(1)(CLO4)] [J].

BARROW, M ;

BURGI, HB ;

CAMALLI, M ;

CARUSO, F ;

FISCHER, E ;

VENANZI, LM ;

ZAMBONELLI, L .

INORGANIC CHEMISTRY, 1983, 22 (17) :2356-2362

[2] SYNTHESIS, PROPERTIES, AND CHARACTERIZATION OF SULFATO AND SELENATO COMPLEXES OF COBALT(II) AND NICKEL(II) WITH 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE (P3) - CRYSTAL AND MOLECULAR-STRUCTURES OF CO(P3)SO4 AND NI(P3)SEO4 [J].

BENELLI, C ;

DIVAIRA, M ;

NOCCIOLI, G ;

SACCONI, L .

INORGANIC CHEMISTRY, 1977, 16 (01) :182-187

[3] SYNTHESIS AND CRYSTAL-STRUCTURE OF 2 ISOMORPHOUS RHODIUM AND IRIDIUM COMPLEXES WITH CYCLO-TRIPHOSPHORUS AND 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)-ETHANE [J].

BIANCHINI, C ;

MEALLI, C ;

MELI, A ;

SACCONI, L .

INORGANICA CHIMICA ACTA, 1979, 37 (02) :L543-L544

[4] HOMOMETAL AND HETEROMETAL TRIPLE-DECKER COMPLEXES OF CYCLO-TRIPHOSPHORUS WITH MIXED TRIPHOSPHINE LIGANDS - CRYSTAL-STRUCTURE OF [[MEC(CH2PPH2)3]CO[MU-(ETA-3-P3)]FE[MEC(CH2PET2)3]](PF6)2.CH2CL2 [J].

BIANCHINI, C ;

DIVAIRA, M ;

MELI, A ;

SACCONI, L .

INORGANIC CHEMISTRY, 1981, 20 (04) :1169-1173

[5] CHEMISTRY OF ET3P.CS2 METAL-COMPLEXES - SYNTHESIS OF 1,1-DITHIOLATE COMPLEXES VIA NUCLEOPHILIC ATTACKS ON [(TRIPHOS)CO(S2CPET3)](BPH4)2 - X-RAY STRUCTURE OF [(TRIPHOS)CO(S2CO)] [J].

BIANCHINI, C ;

MELI, A ;

ORLANDINI, A .

INORGANIC CHEMISTRY, 1982, 21 (12) :4166-4169

[6] SYNTHESIS AND X-RAY STRUCTURE OF THE DINUCLEAR COBALT(0) COMPLEX (PHC=CPH)CO2(CO)4(TRIPHOS) [J].

BIANCHINI, C ;

DAPPORTO, P ;

MELI, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 174 (02) :205-212

[7] PI-POLYOLEFIN AND PI-ACETYLENE COBALT(I) COMPLEXES WITH THE TRIS(TERTIARY PHOSPHINE) 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE - X-RAY STRUCTURE OF [(TRIPHOS)CO(ETA-4-C7H8)]CLO4.0.5CH2CL2 [J].

BIANCHINI, C ;

DAPPORTO, P ;

MELI, A ;

SACCONI, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 193 (01) :117-126

[8]

BURGI HB, 1980, INORG CHEM, V19, P3707

[9] CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(TRICYCLOHEXYLPHOSPHINE)SILVER(I)NITRATE AND BIS(TRICYCLOHEXYLPHOSPHINE)SILVER(I)PERCHLORATE - CORRELATION OF THE STRUCTURES WITH THE SILVER PHOSPHORUS COUPLING-CONSTANTS [J].

CAMALLI, M ;

CARUSO, F .

INORGANICA CHIMICA ACTA, 1988, 144 (02) :205-211

[10] CORRELATION BETWEEN P-31 NMR DATA AND STRUCTURAL PARAMETERS ON AG(PPH3)3X SERIES - CRYSTAL AND MOLECULAR-STRUCTURE OF TRIS(TRIPHENYLPHOSPHINE)SILVER(I)TETRAFLUOROBORATE AND TRIS(TRIPHENYLPHOSPHINE)SILVER(I)IODIDE [J].

CAMALLI, M ;

CARUSO, F .

INORGANICA CHIMICA ACTA, 1987, 127 (02) :209-213

← 1 2 3 4 →