REACTIONS OF DISULFUR DINITRIDE WITH BORON TRIFLUORIDE AND BORON TRICHLORIDE

被引：17

作者：

PATTON, RL

JOLLY, WL

机构：

[1] Department of Chemistry, University of California, Inorganic Materials Research Division, Lawrence Radiation Laboratory, Berkeley

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 07期

关键词：

D O I：

10.1021/ic50077a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Disulfur dinitride reacts with boron trichloride in dichloromethane to form the following compounds (each of which can be obtained as the principal product by suitable choice of reaction conditions): S4N4BCl3, S2N2(BCl3)2, and an apparently polymeric material (S2N2BCl3)x. At 0°, S2N2(BCl3)2 loses BCl3 to form a simple adduct S2N2BCl3 which can be reconverted to the diadduct by treatment with BCl3 at -78°. Whereas SbCl5 displaces BCl5 from S2N2BCl3 to form S2N2(SbCl5)2, the polymeric material (S2N2BCl3)x, is inert toward both BCl3 and SbCl5. The properties ofS2N2BCl3 and S2N2(BCl3)2 indicate that the S2N2 ring structure remains intact. Reaction of S2N2 with BF3 yields only S4N4BF3. © 1969, American Chemical Society. All rights reserved.

引用

页码：1392 / &

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