SYNTHESIS, CHARACTERIZATION AND COPPER INCORPORATION INTO 5-(4-PYRIDYL)-10,15,20-TRIPHENYLPORPHYRIN

被引：38

作者：

WILLIAMS, GN ^{[1
]}

WILLIAMS, RFX ^{[1
]}

LEWIS, A ^{[1
]}

HAMBRIGHT, P ^{[1
]}

机构：

[1] HOWARD UNIV,DEPT CHEM,WASHINGTON,DC 20059

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 01期

关键词：

D O I：

10.1016/0022-1902(79)80390-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

5-(4-Pyridyl)-10,15,20-triphenylporphyrin, H2TriP, and its water insoluble N-Methyl derivative were synthesized. The PMR and phase selective first and second harmonic polarographic studies were consistent with the proposed structure. In either sodium dodecylsulfate or Triton X-100 detergents, only the free base and di-acid porphyrin forms were present. This was confirmed by a copper incorporation study in SDS, which indicated the absence of a mono-cation, reactivity of only the free base form, and no anion catalysis. © 1979.

引用

页码：41 / 44

页数：4

共 12 条

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