A FACILE SYNTHESIS OF SULFOXIDES BY OXIDATION OF SULFIDES WITH SODIUM BROMITE IN AN APROTIC-SOLVENT IN THE PRESENCE OF CLAY-MINERALS

被引：32

作者：

HIRANO, M ^{[1
]}

KUDO, H ^{[1
]}

MORIMOTO, T ^{[1
]}

机构：

[1] TOKYO UNIV AGR & TECHNOL, FAC TECHNOL, DEPT APPL CHEM, KOGANEI, TOKYO 184, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 06期

关键词：

D O I：

10.1246/bcsj.65.1744

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title oxidation has been performed in dichloromethane in the presence of ''wet''-montmorillonite and -kaolin. The substrates studied include dialkyl, alkyl aryl, diaryl, and cyclic sulfides, which give the corresponding sulfoxides in good yields under neutral and mild conditions.

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页码：1744 / 1746

页数：3

相关论文

共 17 条

[1] SULFIDE OXIDATION WITH N-HALOSUCCINIMIDES [J].

HARVILLE, R ;

REED, SF .

JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (10) :3976-&

[2] A CONVENIENT SYNTHESIS OF SULFONES BY THE OXONE OXIDATION OF SULFIDES IN AN APROTIC-SOLVENT IN THE PRESENCE OF CLAY-MINERALS [J].

HIRANO, M ;

TOMARU, J ;

MORIMOTO, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (12) :3752-3754

[3] A FACILE SYNTHESIS OF SULFONES BY THE OXIDATION OF VARIOUS SULFIDES WITH OXONE IN APROTIC-SOLVENT IN THE PRESENCE OF WET-MONTMORILLONITE [J].

HIRANO, M ;

TOMARU, J ;

MORIMOTO, T .

CHEMISTRY LETTERS, 1991, (03) :523-524

[4] A NOVEL SYNTHESIS OF LACTONES BY THE OXIDATION OF ALICYCLIC KETONES WITH OXONE IN APROTIC-SOLVENT IN THE PRESENCE OF WET-ALUMINA [J].

HIRANO, M ;

OOSE, M ;

MORIMOTO, T .

CHEMISTRY LETTERS, 1991, (02) :331-332

[5] OXIDATION OF SEC-ALCOHOLS WITH OXONE IN APROTIC-SOLVENTS IN THE PRESENCE OF WET-ALUMINUM OXIDE [J].

HIRANO, M ;

OOSE, M ;

MORIMOTO, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (03) :1046-1047

[6]

HUDLICKY M, 1990, OXIDATIONS ORGANIC C, P250

[7] CHLORINOLYSIS OF SULFUR-CARBON BONDS IN ARYL-ALKYL SULFIDES [J].

KWART, H ;

MILLER, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (19) :5008-5011

[8]

LASZLO P, 1987, PREPARATIVE CHEM USI, P455

[9] READY OXIDATION OF ALCOHOLS TO CARBONYL-COMPOUNDS BY SODIUM BROMITE IN METHYLENE DICHLORIDE IN THE PRESENCE OF ALUMINUM-OXIDE [J].

MORIMOTO, T ;

HIRANO, M ;

AIKAWA, Y ;

ZHANG, X .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (08) :2423-2424

[10]

NUMATA T, 1982, HANNO KIKOHEN, P163