ENANTIOMERIC RECOGNITION OF ORGANIC AMMONIUM-SALTS BY CHIRAL PYRIDINO-18-CROWN-6 LIGANDS - A SHORT REVIEW

被引：29

作者：

BRADSHAW, JS ^{[1
]}

HUSZTHY, P ^{[1
]}

MCDANIEL, CW ^{[1
]}

OUE, M ^{[1
]}

ZHU, CY ^{[1
]}

IZATT, RM ^{[1
]}

LIFSON, S ^{[1
]}

机构：

[1] WEIZMANN INST SCI,DEPT CHEM PHYS,IL-76100 REHOVOT,ISRAEL

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1992年 / 27卷 / 1-3期

关键词：

CHIRAL PYRIDINO-18-CROWN-6 LIGANDS; CHIRAL ORGANIC AMMONIUM IONS; ENANTIOMERIC RECOGNITION;

D O I：

10.1080/00958979209407947

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A short review of enantiomeric recognition of chiral organic ammonium salts by chiral pyridino-18-crown-6 ligands is presented. Topics include preparation of chiral macrocycles and details of enantiomeric recognition as determined by H-1 NMR and calorimetry techniques. The chiral pyridino-18-crown-6 ligands containing two tert-butyl or two phenyl substituents on chiral macroring carbon atoms exhibited the highest recognition for the enantiomers of [alpha-(1-naphthyl)ethyl]ammonium perchlorate of any chiral pyridino-18-crown-6 ligands studied.

引用

页码：105 / 114

页数：10

共 39 条

[1] HOST GUEST COMPLEXATION .33. SEARCH FOR NEW CHIRAL HOSTS [J].

ARTZ, SP ;

DEGRANDPRE, MP ;

CRAM, DJ .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (09) :1486-1496

[2] TEMPERATURE-DEPENDENT H-1-NMR STUDIES OF THE COMPLEXATION OF SYNTHETIC MACROCYCLIC MULTI-DENTATE COMPOUNDS WITH PRIMARY ALKYLAMMONIUM SALTS - A SHORT REVIEW [J].

BAXTER, SL ;

BRADSHAW, JS .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1981, 18 (02) :233-245

[3] NEW CONVERSION OF ESTERS TO ETHERS AND ITS APPLICATION TO THE PREPARATION OF FURANO-18-CROWN-6 [J].

BAXTER, SL ;

BRADSHAW, JS .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (04) :831-832

[4] THE PREPARATION OF NEW CHIRAL DIPHENYL-SUBSTITUTED MACROCYCLIC POLYETHER-DIESTER COMPOUNDS AND THEIR ENANTIOMERIC RECOGNITION OF CHIRAL ORGANIC AMMONIUM-SALTS [J].

BRADSHAW, JS ;

THOMPSON, PK ;

IZATT, RM ;

MORIN, FG ;

GRANT, DM .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1984, 21 (03) :897-901

[5] PROTON-IONIZABLE CROWN COMPOUNDS .1. SYNTHESIS, COMPLEXATION PROPERTIES, AND STRUCTURAL STUDIES OF MACROCYCLIC POLYETHER DIESTER LIGANDS CONTAINING A TRIAZOLE SUBCYCLIC UNIT [J].

BRADSHAW, JS ;

CHAMBERLIN, DA ;

HARRISON, PE ;

WILSON, BE ;

ARENA, G ;

DALLEY, NK ;

LAMB, JD ;

IZATT, RM .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (17) :3065-3069

[6]

BRADSHAW JS, 1985, J ORG CHEM, V50, P4865

[7] PREPARATION OF CHIRAL DIPHENYL-SUBSTITUTED POLYETHER-DIESTER COMPOUNDS [J].

BRADSHAW, JS ;

JOLLEY, ST ;

IZATT, RM .

JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (07) :1229-1232

[8] ENANTIOMERIC RECOGNITION OF ORGANIC AMMONIUM-SALTS BY CHIRAL DIALKYL-SUBSTITUTED, DIALKENYL-SUBSTITUTED, AND TETRAMETHYL-SUBSTITUTED PYRIDINO-18-CROWN-6 AND TETRAMETHYL-SUBSTITUTED BIS-PYRIDINO-18-CROWN-6 LIGANDS - COMPARISON OF TEMPERATURE-DEPENDENT H-1-NMR AND EMPIRICAL FORCE-FIELD TECHNIQUES [J].

BRADSHAW, JS ;

HUSZTHY, P ;

MCDANIEL, CW ;

ZHU, CY ;

DALLEY, NK ;

IZATT, RM ;

LIFSON, S .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (10) :3129-3137

[9] CATION COMPLEXING PROPERTIES OF SYNTHETIC MACROCYCLIC POLYETHER-DIESTER LIGANDS CONTAINING THE PYRIDINE SUBCYCLIC UNIT [J].

BRADSHAW, JS ;

MAAS, GE ;

LAMB, JD ;

IZATT, RM ;

CHRISTENSEN, JJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) :467-474

[10] CHIRAL DIAZA-18-CROWN-6 DERIVATIVES [J].

CHADWICK, DJ ;

CLIFFE, IA ;

SUTHERLAND, IO .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (19) :992-994

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