EXCHANGE OF AZINE LIGANDS IN FAC-RE(CO)3(4-CYANOPYRIDINE)2CL AND FAC-RE(CO)3(QUINOLINE)2CL

被引：6

作者：

FERRAUDI, G

IHA, NM

RUIZ, G

WOLCAN, E

FELIZ, ME

机构：

[1] Radiation Laboratory, University of Notre Dame, Notre Dame

来源：

INORGANICA CHIMICA ACTA | 1994年 / 221卷 / 1-2期

基金：

巴西圣保罗研究基金会;

关键词：

RHENIUM COMPLEXES; CARBONYL COMPLEXES; AMINE COMPLEXES; AZINE COMPLEXES;

D O I：

10.1016/0020-1693(94)03953-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One of the azine ligands in fac-Re(CO)3L2Cl, L = 4-cyanopyridine or quinoline, was found to be more labile than in other related Re(I) complexes. Substitution of 4-cyanopyridine by 4-phenylpyridine in fac-Re(CO)3(4-cyanopyridine)2Cl was successfully applied to the preparation of fac-Re(CO)3(4-cyanopyridine)(4-phenylpyridine)Cl. The kinetics of the mixed-ligand complex formation was investigated and a reaction mechanism is proposed.

引用

页码：161 / 164

页数：4

共 8 条

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